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Lime-soda ash treatment for the reduction of hardness involves the addition of slake lime [Ca(OH)2] to a hard water supply to remove the carbonate hardness by precipitation with the precipitation being removed by filtration. Non-carbonate hardness is in turn reduced by the addition of soda ash (Na2C03) to form insoluble precipitate which is also removed by filtration.
This particular method of removing hardness sometimes used by municipal water plants to reduce the amount of calcium and magnesium in a water supply. While it is quite effective in reducing hardness, it is not a complete removal treatment.
Often when a city has a raw water source that has 35 to 40 grain hard water, the local water system will use the lime-soda ash treatment to reduce hardness to between 5 and 10 grains.
Lime-soda ash treatment is especially effective if a water contains bicarbonate (temporary) hardness. Where calcium and magnesium are primarily in chloride or sulfate compounds, this treatment is noticeably less effective.
Slaked lime is used to remove calcium bicarbonate from water. In the water to be treated, the slaked lime ions react with the calcium bicarbonate to form the very slightly soluble calcium carbonate. This precipitated material is usually removed by first settling and then filtering.
Ca(OH) 2+ Ca(HC03)2 --> 2 CaCO3 + 2 H2O
Calcium hydroxide plus calcium bicarbonate reacts to form calcium carbonate plus water
NOTE: The arrow pointing down (¥) indicates the formation of an insoluble compound.
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